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Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

《能源前沿（英文）》 2019年 第13卷 第4期   页码 770-797 doi: 10.1007/s11708-019-0651-x

摘要： Recently, the development and fabrication of electrode component of the solid oxide fuel cell (SOFC) have gained a significant importance, especially after the advent of electrode supported SOFCs. The function of the electrode involves the facilitation of fuel gas diffusion, oxidation of the fuel, transport of electrons, and transport of the byproduct of the electrochemical reaction. Impressive progress has been made in the development of alternative electrode materials with mixed conducting properties and a few of the other composite cermets. During the operation of a SOFC, it is necessary to avoid carburization and sulfidation problems. The present review focuses on the various aspects pertaining to a potential electrode material, the double perovskite, as an anode and cathode in the SOFC. More than 150 SOFCs electrode compositions which had been investigated in the literature have been analyzed. An evaluation has been performed in terms of phase, structure, diffraction pattern, electrical conductivity, and power density. Various methods adopted to determine the quality of electrode component have been provided in detail. This review comprises the literature values to suggest possible direction for future research.

关键词： double perovskites     electrode materials     hydrocarbon fuel     solid oxide fuel cells    

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High performance solid-state thermoelectric energy conversion via inorganic metal halide perovskites

Lifu YAN, Lingling ZHAO, Guiting YANG, Shichao LIU, Yang LIU, Shangchao LIN

《能源前沿（英文）》 2022年 第16卷 第4期   页码 581-594 doi: 10.1007/s11708-022-0831-y

摘要： Solid-state thermoelectric energy conversion devices attract broad research interests because of their great promises in waste heat recycling, space power generation, deep water power generation, and temperature control, but the search for essential thermoelectric materials with high performance still remains a great challenge. As an emerging low cost, solution-processed thermoelectric material, inorganic metal halide perovskites CsPb(I1–xBrx)3 under mechanical deformation is systematically investigated using the first-principle calculations and the Boltzmann transport theory. It is demonstrated that halogen mixing and mechanical deformation are efficient methods to tailor electronic structures and charge transport properties in CsPb(I1–xBrx)3 synergistically. Halogen mixing leads to band splitting and anisotropic charge transport due to symmetry-breaking-induced intrinsic strains. Such band splitting reconstructs the band edge and can decrease the charge carrier effective mass, leading to excellent charge transport properties. Mechanical deformation can further push the orbital energies apart from each other in a more controllable manner, surpassing the impact from intrinsic strains. Both anisotropic charge transport properties andZT values are sensitive to the direction and magnitude of strain, showing a wide range of variation from 20% to 400% (with a ZT value of up to 1.85) compared with unstrained cases. The power generation efficiency of the thermoelectric device can reach as high as approximately 12% using mixed halide perovskites under tailored mechanical deformation when the heat-source is at 500 K and the cold side is maintained at 300 K, surpassing the performance of many existing bulk thermoelectric materials.

关键词： inorganic metal halide perovskites     mechanical deformation     thermoelectrics     first-principle calculations     Boltzmann transport theory    

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Reduction of CeO

Elena Yu. KONYSHEVA

《化学科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 249-261 doi: 10.1007/s11705-013-1333-6

摘要： Reduction behavior of pure and doped CeO , the multi-phase La Sr CoO ? CeO , La Sr MnO ? CeO , and La Ni Fe O ? CeO composites, was studied under hydrogen containing atmosphere to address issues related to the improvement of electrochemical and catalytic performance of electrodes in fuel cells. The enhanced reduction of cerium oxide was observed initially at 800°C in all composites in spite of the presence of highly reducible transition metal cations that could lead to the increase in surface concentration of oxygen vacancies and generation of the electron enriched surface. Due to continuous reduction of cerium oxide in La Sr CoO ? CeO and La Sr MnO ? CeO (up to 10 h) composites the redox activity of the Ce /Ce pair could be suppressed and additional measures are required for reversible spontaneous regeneration of Ce . After 3 h exposure to H -Ar at 800°C the reduction of cerium oxides and perovskite phases in La Ni Fe O ? CeO composites was diminished. The extent of cerium oxide involvement in the reduction process varies with time, and depends on its initial deviation from oxygen stoichiometry (that results in the larger lattice parameter and the longer pathway for O transport through the fluorite lattice), chemical origin of transition metal cations in the perovskite, and phase diversity in multi-phase composites.

关键词： reduction of cerium oxide     composites     perovskites     catalyst under hydrogen containing atmosphere    

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Mature

Giorgia De Guido, Matteo Compagnoni, Laura A. Pellegrini, Ilenia Rossetti

《化学科学与工程前沿（英文）》 2018年 第12卷 第2期   页码 315-325 doi: 10.1007/s11705-017-1698-z

摘要： Carbon capture and storage (CCS) have acquired an increasing importance in the debate on global warming as a mean to decrease the environmental impact of energy conversion technologies, by capturing the CO produced from the use of fossil fuels in electricity generation and industrial processes. In this respect, post-combustion systems have received great attention as a possible near-term CO capture technology that can be retrofitted to existing power plants. This capture technology is, however, energy-intensive and results in large equipment sizes because of the large volumes of the flue gas to be treated. To cope with the demerits of other CCS technologies, the chemical looping combustion (CLC) process has been recently considered as a solution for CO separation. It is typically referred to as a technology without energy penalty. Indeed, in CLC the fuel and the combustion air are never mixed and the gases from the oxidation of the fuel (i.e., CO and H O) leave the system as a separate stream and can be separated by condensation of H O without any loss of energy. The key issue for the CLC process is to find a suitable oxygen carrier, which provides the fuel with the activated oxygen needed for combustion. The aim of this work is to explore the feasibility of using perovskites as oxygen carriers in CLC and to consider the possible advantages with respect to the scrubbing process with amines, a mature post-combustion technology for CO separation.

关键词： CO2 capture     monoethanolamine     chemical looping combustion     oxygen carrier     perovskites    

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Experimental measurement of double-K fracture parameters of concrete with small-size aggregates

ZHANG Xiufang, XU Shilang, ZHENG Shuang

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 448-457 doi: 10.1007/s11709-007-0061-8

摘要： The double- fracture model can well describe the development of cracks undergoing during the entire fracture process in concrete. Therefore, it has been selected as the theoretical basis of the Norm for fracture test of

关键词： development     concrete     theoretical     double- fracture    

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Numerical study of thermal characteristics of double skin facade system with middle shade

Shaoning LIU, Xiangfei KONG, Hua YANG, Minchao FAN, Xin ZHAN

《能源前沿（英文）》 2021年 第15卷 第1期   页码 222-234 doi: 10.1007/s11708-017-0480-8

摘要： Architectural shade is an effective method for improving building energy efficiency. A new shade combined with the double skin façade (DSF) system, called middle shade (MS), was introduced and developed for buildings. In this paper, a 3D dynamic simulation was conducted to analyze the influence of MS combined with DSF on the indoor thermal characteristics. The research on MS for DSF involves the temperature, the ventilation rate, the velocity distribution of the air flow duct, and the indoor temperature. The results show that the angle and position of the shade in the three seasons are different, and different conditions effectively enhance the indoor thermal characteristics. In summer, the appearance of MS in DSF makes the indoor temperature significantly lower. The indoor temperature is obviously lower than that of the air flow duct, and the temperature of the air flow duct is less affected by MS. The influence of the position of blinds on indoor temperature and ventilation rate is greater than the influence of the angle of blinds. According to the climate characteristics of winter and transition season, in winter, early spring, and late autumn, the indoor temperature decreases with the increase of the position of blinds at daytime, but the opposite is true at night. The results found in this paper can provide reference for the design and use of MS combined with DSF in hot summer and cold winter zone.

关键词： middle shade     position     thermal characteristics     double skin facade    

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Moment-curvature relationship of FRP-concrete-steel double-skin tubular members

Mingxue LIU, Jiaru QIAN

《结构与土木工程前沿（英文）》 2009年 第3卷 第1期   页码 25-31 doi: 10.1007/s11709-009-0012-7

摘要： Tests were conducted on 3 specimens to study the flexural behavior of fiber reinforced polymer (FRP)-concrete-steel double-skin tubular members (DSTMs). The strip method was used to calculate the section moment-curvature curves of the 3 specimens and 12 models. A theoretical formula is presented for the flexural strength of DSTMs. The test results show that the tension zone of the specimen FRP tubes was in hoop compression while the compression zone was in hoop tension. The load-carrying capacity did not decrease even when the mid-span deflection reached about 1/24 of the span length. The tests, simulation and theoretical analysis resulted in a simplified formula for the flexural strength of DSTMs and a tri-linear moment-curvature model was expressed as a function of the section bending stiffness for DSTMs.

关键词： fiber reinforced polymer (FRP)     concrete     steel     double-skin tubular members (DSTMs)     moment-curvature curve     flexural strength    

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Enhancement of distillate output of double basin solar still with vacuum tubes

Hitesh N PANCHAL, P K SHAH

《能源前沿（英文）》 2014年 第8卷 第1期   页码 101-109 doi: 10.1007/s11708-014-0299-5

摘要： The latent heat of condensation is lost to the atmosphere; hence it is not utilized to increase distillate output of single basin solar stills. This difficulty was overcome by attaching an additional basin to the main basin. The performance of the double basin solar still was also increased by attaching vacuum tubes to the lower basin; hence the lower basin possessed a higher temperature throughout the day. The latent heat of condensation of the bottom basin was also utilized to increase distillate. But the distillate output of the top basin was even lower compared with that of the bottom basin. This paper proposed a novel approach to increase the distillate output of the double basin solar still attached with vacuum tubes by introducing different sensible energy storage materials like pebbles, black granite gravel and calcium stones to increase the basin area. Experiments were conducted in climate conditions of Mehsana (23.6000° N, 72.4000° E) Gujarat from April to September 2013 with a constant water depth of 2 cm in the top basin with and without the use of basin materials. The results showed that the distillate output of basin material with calcium stones is greater (74%) compared with that of black granite gravel and pebbles. The integration of vacuum tubes with solar still greatly increases the distillate output of the solar still by providing hot water at the lower basin.

关键词： double basin solar still     calcium stones     pebbles     granite gravel     distillate output    

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Nanosilver anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficient

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 893-905 doi: 10.1007/s11705-022-2290-8

摘要： A novel alginate/poly(acrylic acid/acrylamide) double-network hydrogel composite with silver nanoparticles was successfully fabricated using the sol–gel method. The presence of carboxyl and amide groups in the network structure provided abundant active sites for complexing silver ions, facilitating the in situ reduction and confinement of silver nanoparticles. In batch experiments, the optimal silver loading was 20%, and 5 mmol·L–1 of p-nitrophenol was completely degraded in 113 s with a rate constant value of 4.057 × 10−2 s–1. In the tap water system and simulated seawater system, the degradation time of p-nitrophenol at the same concentration was 261 and 276 s, respectively, with a conversion rate above 99%. In the fixed-bed experiment, the conversion rate remained above 74% after 3 h at a flowing rate of 7 mL·min–1. After 8 cycling tests, the conversion rate remained at 98.7%. Moreover, the catalyst exhibited outstanding performance in the degradation experiment of four typical organic dyes.

关键词： double-network hydrogel     dye degradation     silver nanoparticles     alginate    

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Synergistic effect of V and Fe in Ni/Fe/V ternary layered double hydroxides for efficient and durable

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 102-115 doi: 10.1007/s11705-022-2179-6

摘要： High-performance and stable electrocatalysts are vital for the oxygen evolution reaction (OER). Herein, via a one-pot hydrothermal method, Ni/Fe/V ternary layered double hydroxides (NiFeV-LDH) derived from Ni foam are fabricated to work as highly active and durable electrocatalysts for OER. By changing the feeding ratio of Fe and V salts, the prepared ternary hydroxides were optimized. At an Fe:V ratio of 0.5:0.5, NiFeV-LDH exhibits outstanding OER activity superior to that of the binary hydroxides, requiring overpotentials of 269 and 274 mV at 50 mA·cm–2 in the linear sweep voltammetry and sampled current voltammetry measurements, respectively. Importantly, NiFeV-LDH shows extraordinary long-term stability (≥ 75 h) at an extremely high current density of 200 mA·cm–2. In contrast, the binary hydroxides present quick decay at 200 mA·cm–2 or even reduced current densities (150 and 100 mA·cm–2). The outstanding OER performance of NiFeV-LDH benefits from the synergistic effect of V and Fe while doping the third metal into bimetallic hydroxide layers: (a) Fe plays a crucial role as the active site; (b) electron-withdrawing V stabilizes the high valence state of Fe, thus accelerating the OER process; (c) V further offers great stabilization for the formed intermediate of FeOOH, thus achieving superior durability.

关键词： oxygen evolution reaction     electrocatalysts     ternary layered double hydroxides     long-term stability    

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Prediction and cause investigation of ozone based on a double-stage attention mechanism recurrent neural

《环境科学与工程前沿（英文）》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1621-4

摘要：

● Used a double-stage attention mechanism model to predict ozone.

关键词： Ozone prediction     Deep learning     Time series     Attention     Volatile organic compounds    

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FBRM and PVM investigations of the double feed semi-batch crystallization of 6-aminopenicillanic acid

Min SU, Lin WANG, Hua SUN, Jingkang WANG

《化学科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 282-288 doi: 10.1007/s11705-009-0018-7

摘要： 6-Aminopenicillanic acid (6-APA) is a crucial pharmaceutical intermediate in the chemistry of semi-synthetic antibiotics. The focused beam reflectance measurement (FBRM) technology and particle vision measurement (PVM) technology were employed to the processes of online-monitoring of 6-APA crystallization behavior in a double-feeding semi-batch crystallizer. Experiments were carried out with four kinds of double-feeding policies and the results were compared with the traditional single-feeding. Records and analysis of FBRM indicated that the nucleation of double feeding policy was much higher than single policy, and chord length of 6-APA was almost determined and had little change after the nucleation peak. Ostwald ripening process had no significant effect on further growth of 6-APA crystal. PVM images showed that the crystal habit of 6-APA was continuously changed during the crystallization process. The development of (002) face in the final crystal for the five feeding policies were different.

关键词： 6-aminopenicillanic acid     crystallization     double-feeding     FBRM     PVM     crystal habit    

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Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layered double

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1593-1607 doi: 10.1007/s11705-023-2348-2

摘要： With increasing emphasis on green chemistry, biomass-based materials have attracted increased attention regarding the development of highly efficient functional materials. Herein, a new pore-rich cellulose nanofibril aerogel is utilized as a substrate to integrate highly conductive polypyrrole and active nanoflower-like nickel-cobalt layered double hydroxide through in situ chemical polymerization and electrodeposition. This ternary composite can act as an effective self-supported electrode for the electrocatalytic oxidation of glucose. With the synergistic effect of three heterogeneous components, the electrode achieves outstanding glucose sensing performance, including a high sensitivity (851.4 µA·mmol−1·L·cm−2), a short response time (2.2 s), a wide linear range (two stages: 0.001−8.145 and 8.145−35.500 mmol·L−1), strong immunity to interference, outstanding intraelectrode and interelectrode reproducibility, a favorable toxicity resistance (Cl‒), and a good long-term stability (maintaining 86.0% of the original value after 30 d). These data are superior to those of some traditional glucose sensors using nonbiomass substrates. When determining the blood glucose level of a human serum, this electrode realizes a high recovery rate of 97.07%–98.89%, validating the potential for high-performance blood glucose sensing.

关键词： cellulose nanofibril     aerogel     nickel-cobalt layered double hydroxide     polypyrrole     nonenzymatic glucose sensor    

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Stability analysis and optimization of excavation method of double-arch tunnel with an extra-large span

Yiguo XUE, Huimin GONG, Fanmeng KONG, Weimin YANG, Daohong QIU, Binghua ZHOU

《结构与土木工程前沿（英文）》 2021年 第15卷 第1期   页码 136-146 doi: 10.1007/s11709-020-0710-8

摘要： The Xiamen Haicang double-arch tunnel has a maximum span of 45.73 m and a minimum burial depth of 5.8 m. A larger deformation or collapse of the tunnel is readily encountered during tunnel excavation. It is therefore necessary to select a construction approach that is suitable for double-arch tunnel projects with an extra-large span. In this study, three construction methods for double-arch tunnels with extra-large spans were numerically simulated. Subsequently, the deformation behavior and stress characteristics of the surrounding rock were obtained and compared. The results showed that the double-side-drift method with temporary vertical support achieves better adaptability in the construction of such tunnels, which can be observed from both the numerical results and monitoring data. In addition, the improved temporary support plays a critical role in controlling the surrounding rock deformation. In addition, the disturbance resulting from the excavation of adjacent drifts was obvious, particularly the disturbance of the surrounding rock caused by the excavation of the middle drift. The present findings can serve as the initial guidelines for the construction of ultra-shallowly buried double-arch tunnels with extra-large spans.

关键词： double-arch tunnel     triple-layer composite liner system     numerical modeling     stress analysis     settlement    

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Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 613-623 doi: 10.1007/s11705-017-1664-9

摘要： Carbon deposition and sintering of active components such as nano particles are great challenges for Ni-based catalysts for CO methanation to generate synthetic natural gas from syngas. Facing the challenges, bimetallic catalysts with different Fe content derived from layered double hydroxide containing Ni, Fe, Mg, Al elements were prepared by co-precipitation method. Nanoparticles of Ni-Fe alloy were supported on mixed oxides of aluminium and magnesium after calcination and reduction. The catalysts were characterized by Brunner-Emmett-Teller (BET), X-ray diffraction, hydrogen temperature programmed reduction, inductively coupled plasma, X-ray photoelectron spectroscopy, transmission electron microscopy and thermogravimetric techniques, and their catalytic activity for CO methanation was investigated. The results show that the Ni-Fe alloy catalysts exhibit better catalytic performance than monometallic catalysts except for the Ni4Fe-red catalyst. The Ni2Fe-red catalyst shows the highest CO conversion (100% at 260–350 °C), as well as the highest CH selectivity (over 95% at 280–350 °C), owing to the formation of Ni-Fe alloy. In stability test, the Ni2Fe-red catalyst exhibits great improvement in both anti-sintering and resistance to carbon formation compared with the Ni0Fe-red catalyst. The strong interaction between Ni and Fe element in alloy and surface distribution of Fe element not only inhibits the sintering of nanoparticles but restrains the formation of Ni clusters.

关键词： methanation     layered double hydroxide     bimetal Ni-Fe alloy     sintering     carbon deposition    

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标题 作者 时间 类型 操作

Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

期刊论文

High performance solid-state thermoelectric energy conversion via inorganic metal halide perovskites

Lifu YAN, Lingling ZHAO, Guiting YANG, Shichao LIU, Yang LIU, Shangchao LIN

期刊论文

Reduction of CeO

Elena Yu. KONYSHEVA

期刊论文

Mature

Giorgia De Guido, Matteo Compagnoni, Laura A. Pellegrini, Ilenia Rossetti

期刊论文

Experimental measurement of double-K fracture parameters of concrete with small-size aggregates

ZHANG Xiufang, XU Shilang, ZHENG Shuang

期刊论文

Numerical study of thermal characteristics of double skin facade system with middle shade

Shaoning LIU, Xiangfei KONG, Hua YANG, Minchao FAN, Xin ZHAN

期刊论文

Moment-curvature relationship of FRP-concrete-steel double-skin tubular members

Mingxue LIU, Jiaru QIAN

期刊论文

Enhancement of distillate output of double basin solar still with vacuum tubes

Hitesh N PANCHAL, P K SHAH

期刊论文

Nanosilver anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficient

期刊论文

Synergistic effect of V and Fe in Ni/Fe/V ternary layered double hydroxides for efficient and durable

期刊论文

Prediction and cause investigation of ozone based on a double-stage attention mechanism recurrent neural

期刊论文

FBRM and PVM investigations of the double feed semi-batch crystallization of 6-aminopenicillanic acid

Min SU, Lin WANG, Hua SUN, Jingkang WANG

期刊论文

Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layered double

期刊论文

Stability analysis and optimization of excavation method of double-arch tunnel with an extra-large span

Yiguo XUE, Huimin GONG, Fanmeng KONG, Weimin YANG, Daohong QIU, Binghua ZHOU

期刊论文

Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

期刊论文